Experimental and computational study of methane and methyl formate pyrolysis and oxidation in a flow reactor

Campanelli, Carlo (2013) Experimental and computational study of methane and methyl formate pyrolysis and oxidation in a flow reactor. [Laurea magistrale], Università di Bologna, Corso di Studio in Chimica industriale [LM-DM270], Documento ad accesso riservato.
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Abstract

A study of the pyrolysis and oxidation (phi 0.5-1-2) of methane and methyl formate (phi 0.5) in a laboratory flow reactor (Length = 50 cm, inner diameter = 2.5 cm) has been carried out at 1-4 atm and 300-1300 K temperature range. Exhaust gaseous species analysis was realized using a gas chromatographic system, Varian CP-4900 PRO Mirco-GC, with a TCD detector and using helium as carrier for a Molecular Sieve 5Å column and nitrogen for a COX column, whose temperatures and pressures were respectively of 65°C and 150kPa. Model simulations using NTUA [1], Fisher et al. [12], Grana [13] and Dooley [14] kinetic mechanisms have been performed with CHEMKIN. The work provides a basis for further development and optimization of existing detailed chemical kinetic schemes.

Abstract
Tipologia del documento
Tesi di laurea (Laurea magistrale)
Autore della tesi
Campanelli, Carlo
Relatore della tesi
Scuola
Corso di studio
Ordinamento Cds
DM270
Parole chiave
methane methyl formate pyrolysis oxidation flow reactor
Data di discussione della Tesi
18 Ottobre 2013
URI

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