Analysis of the high-resolution ro-vibrational spectrum of DC3N in the far and mid infrared regions

Adamczyk, Aleksandra Katarzyna (2020) Analysis of the high-resolution ro-vibrational spectrum of DC3N in the far and mid infrared regions. [Laurea magistrale], Università di Bologna, Corso di Studio in Chimica industriale [LM-DM270]
Documenti full-text disponibili:
[img] Documento PDF (Thesis)
Disponibile con Licenza: Creative Commons: Attribuzione - Non commerciale - Non opere derivate 4.0 (CC BY-NC-ND 4.0)

Download (1MB)


Cyanoacetylene HC3N is a molecule of great astronomical importance and it has been observed in many interstellar environments. Its deuterated form DC3N has been detected in number of sources from external galaxies to Galactic interstellar clouds, star-forming regions and planetary atmospheres. All these detections relied on previous laboratory investigations, which however still lack some essential information concerning its infrared spectrum. In this project, high-resolution ro-vibrational spectra of DC3N have been recorded in two energy regions: 150 – 450 cm-1 and 1800 – 2800 cm-1. In the first window the ν7← GS, 2ν7 ← ν7, ν5 ← ν7, ν5+ν7 ← 2ν7, ν6+ν7 → 2v7, 4ν7 ← 2ν7 bands have been assigned, while in the second region the three stretching fundamental bands ν1, ν2, ν3 have been observed and analysed. The 150 – 450 cm-1 region spectra have been recorded at the AILES beamline at the SOLEIL synchrotron (France), the 1800 – 2800 cm-1 spectra at the Department of Industrial Chemistry “Toso Montanari” in Bologna. In total, 2299 transitions have been assigned. Such experimental transition, together with data previously recorded for DC3N, were included in a least-squares fitting procedure from which several spectroscopic parameters have been determined with high precision and accuracy. They include rotational, vibrational and resonance constants. The spectroscopic data of DC3N have been included in a line catalog for this molecule in order to assist future astronomical observations and data interpretation. A paper which includes this research work has been published (M. Melosso, L. Bizzocchi, A. Adamczyk, E. Cane, P. Caselli, L. Colzid, L. Dorea, B. M. Giulianob, J.-C. Guillemine, M-A. Martin-Drumel, O. Piralif, A. Pietropolli Charmet , D. Prudenzano, V. M. Rivillad, F. Tamassia, Extensive ro-vibrational analysis of deuterated-cyanoacetylene (DC3N) from millimeter wavelengths to the infrared domain, Jour. of Quant. Spectr. and Rad. Tran. 254, 107221, 2020).

Tipologia del documento
Tesi di laurea (Laurea magistrale)
Autore della tesi
Adamczyk, Aleksandra Katarzyna
Relatore della tesi
Correlatore della tesi
Corso di studio
Advanced Spectroscopy in Chemistry
Ordinamento Cds
Parole chiave
cyanoacetylene ro-vibrational spectroscopy spectral analysis
Data di discussione della Tesi
19 Ottobre 2020

Altri metadati

Statistica sui download

Gestione del documento: Visualizza il documento