Synthesis of heteroleptic Cu(I) complexes based on quinolin-yl-1H-1,2,3-triazole

Luci, Luisa (2018) Synthesis of heteroleptic Cu(I) complexes based on quinolin-yl-1H-1,2,3-triazole. [Laurea magistrale], Università di Bologna, Corso di Studio in Chimica industriale [LM-DM270]
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In this work, three mononuclear and five binuclear heteroleptic copper(I) complexes based on quinolin-yl-1H-1,2,3-triazole as diimine chelating ligand and DPEPhos as chelating diphosphine were successful synthesised, these compounds may be good alternative to more expensive photosensitizer based on ruthenium complexes. They show good absorption in visible region and good luminescence in solution at room temperature with long-lived excited states. The most promising complexes, which show adequate photophysical characteristics, such as high PLQY and long-lived luminescence lifetimes will be used to prove their activity in the photocatalytic reduction of CO2.

Tipologia del documento
Tesi di laurea (Laurea magistrale)
Autore della tesi
Luci, Luisa
Relatore della tesi
Correlatore della tesi
Corso di studio
Ordinamento Cds
Parole chiave
photosensitizer carbon dioxide reduction heteroleptic copper(I) complexes
Data di discussione della Tesi
12 Ottobre 2018

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