Synthesis and characterization of polymeric ionic liquid through free radical polymerization of acryloyl imidazolium-based ionic liquid monomer

Marcolongo, Alberto (2015) Synthesis and characterization of polymeric ionic liquid through free radical polymerization of acryloyl imidazolium-based ionic liquid monomer. [Laurea magistrale], Università di Bologna, Corso di Studio in Chimica industriale [LM-DM270], Documento ad accesso riservato.
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Abstract

This thesis investigates the synthesis of polymeric ionic liquid [(poly-acryloyloxy)6C6C1im][NTf2], by free radical polymerization of acryloyl imidazolium-base ionic liquid monomer [(acryloyloxy)6C6C1im][NTf2]. Moreover, the smartest synthetic route to obtain this monomer was investigated. Two different synthesis were compared. The first one started from the preparation of the monomer 6-chlorohexyl acrylate followed by substitution and metathesis to reach ionic liquid monomer. The second one started from synthesis of the ionic liquid [(HO)6C6C1im]Cl followed by metathesis and esterification in order to get ionic liquid monomer [(acryloyloxy)6C6C1im][NTf2].

Abstract
Tipologia del documento
Tesi di laurea (Laurea magistrale)
Autore della tesi
Marcolongo, Alberto
Relatore della tesi
Scuola
Corso di studio
Parole chiave
polymeric ionic liquid monomeric ionic liquid ionic liquid polyelectrolytes polymerization
Data di discussione della Tesi
27 Marzo 2015
URI

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